Both intergranular ig and transgranular tg scc in uhsss has been attributed to. Occasionally, both types of cracking are observed in a failure. Stress corrosion cracking in pipelines sciencedirect. The process of cracking is not strictly a mechanical process, as the corrosivity of the environment strongly affects the fracture mode. Stress corrosion cracking can be either transgranular or intergranular. Scc can be transgranular or intergranular and is found over a limited potential range in environments that promote passive behavior of the. Stress corrosion cracking intergranular scc of an inconel heat exchanger tube with the crack following the grain boundaries.
Intergranular and transgranular stress corrosion cracking. This paper reports that the results indicate that the mechanisms of intergranular stress corrosion cracking and transgranular stress corrosion cracking of cu30 au are identical. Stress corrosion cracking scc is an environmentallydriven failure mechanism that can be found in metal alloys of all types including pure metals. Intergranular scc the cracks which propagate along the grain boundaries called as intergranular stress corrosion cracking as shown in the following figures. Stress corrosion cracking can proceed in one of two ways. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1 environments. Scc requires a tensile stress and a corrosive environment. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
Although intergranular stress corrosion cracking igscc of highpressure gas pipelines has been known for more than 20 years, a transgranular form tgscc was detected more recently. A computational model for intergranular stress corrosion cracking thesis by juli an j. Highpurity copper is immune to stress corrosion cracking in most. In our previous research, the transgranular stress corrosion cracking behavior. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Simulation of inter and transgranular crack propagation. Crystal plasticity, stress corrosion cracking, intergranular crack propagation, intergranulartransgranular transition, finite elements 1. This led to the stress value of stress corrosion cracking, corrosion medium than there is no need of material stress fracture is much smaller.
Ways of propagation of scc scc can proceed in either of two ways. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Stress corrosion cracking scc is a result of synergic interaction of mechanical tension and chemical reaction. Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys. Some studies reported that stress corrosion cracking scc in.
Selective dissolution of the pearlite nodules, which can be catalyzed by chlorides, occurs in fge and this effect stops the propagation of the intergranular scc crack leading to a localized corrosion at the pearlite nodule. The exact degree to which any of these alloys is resistant to any form of corrosion or stress corrosion depends upon its composition, microstructure, and the exact nature of the solution and solution temperature to which it is exposed. Stress corrosion of austenitic steels is usually transgranular. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film. Intergranular corrosion what is intergranular corrosion. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking igscc or simply intergranular corrosion cracking. The results indicate that the electrochemical contribution to the scc of cu30au in 0. This is, of course, a very complex question for a forum like this. Stress corrosion cracking scc is the cracking induced from the combined influence. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain.
Nickel alloys, stainless steels ss, aluminum alloys and other metallic alloys are susceptible to scc. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. When subjected to an external stress or when it is left under residual stress when in contact with certain corrosive environments many alloys will develop cracks which propergate in either intergranular or transgranular mode. Stress corrosion cracking of carbon steel in ethanol. In the introduction to stress corrosion cracking on canadian oil and gas pipelines the neb notes.
Dislocation substructure vs transgranular stress corrosion. Mechanistic differences in transgranular and intergranular. Crack growth is driven by the inelastic deformation at the sharp crack tip. Chloride is the leading cause of transgranular cracking. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in ct environments. Stress corrosion cracking odonnell consulting engineers. At low values of stress, failure occurred by brittle intergranular cracking, and at high values of stress, failure occurred by brittle transgranular cracking. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Transgranular stress corrosion cracking an overview. Transgranular stress corrosion cracking tgscc is the same as igscc, but.
Our awareness of scc on the canadian pipelines we regulate began in 1985. Intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the external pipe surface. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Intergranular stress corrosion cracking transgranular stress corrosion cracking 14. Transgranular attack has a very characteristic branching habit which is easily recognizable in scanning electron microscopy sem fractographic and metallographic section examination. Intergranular stress corrosion cracking of welded steel twi.
If the sample was simultaneously stressed and dealloyed, the fracture mode was transgranular cleavage. R moli in partial ful llment of the requirements for the degree of doctor of philosophy california institute of technology pasadena, california 2009 defended may 5, 2009. Intergranular corrosion facts and how to reduce the risk. It follows the pattern of grains in the individual lattices of the material. Intergranular stress corrosion cracking of copper a case study. Both intergranular and transgranular stress corrosion cracking are observed. The interaction of corrosion fatigue and stresscorrosion. Both intergranular and transgranular stress corrosion cracking are.
Stress corrosion cracking starts from corrosion sites at the material surfaces and progresses into a brittle manner. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. The tensile stress is usually residual stress from welding but also can be caused by mechanical damage or cold forming. Observations of intergranular stress corrosion cracking in. However, the stress corrosion cracking scc of 304 stainless. Internal stress corrosion cracking of shale gas flowlines. In alloys, the active path for preferential electrochemical attack during transgranular stress corrosion cracking is associated with a continuous plane of disordered material which is created by the motion of dislocations through a matrix of shortrange order. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. There appears to be no unique mechanism of transgranular stress corrosion cracking, since no single factor is common to all susceptible alloys. Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks. At the micro level, through the grain as transgranular cracks crack extension along the grain boundaries as intergranular cracks map crack, when the stress corrosion. Characterization of the fracture surface was made using sem and semeds.
Cracks may propagate along the grain boundaries igscc intergranular stress corrosion cracking or 2. With high enough stress level the intergranular scc mechanism can change to transgranular scc cracking at the pearlite. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. A computational model for intergranular stress corrosion. Stress corrosion cracking behavior of nickel base alloys. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Why is chloride stress corrosion cracking transgranular. This post will cover essential information about two forms of corrosion chosen by me, that are intergranular corrosion and stress corrosion. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Transgranular stress corrosion cracking of highpressure. Intergranular stress corrosion cracking scc was produced in ethanolgasoline blend with 15. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Characterization of intergranular stress corrosion. Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking.
The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. It is associated with the simultaneous presence of a number of factors. This form of corrosion cracking is caused by a combination of tensile stresses on the material in the presence of corrosive conditions. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007.
The mechanism of stress corrosion cracking scc of cu30au in 0. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. The mechanism of cracking in both these modes and the conditions under which the transi. Stress corrosion cracking scc is a very common cause of failures for the. What is intergranular stress corrosion cracking igscc. Both intergranular and transgranular stress corrosion cracking is. The alloy composition and structure influence the scc susceptibility 14.
Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1. Both of type 304 and type 316 stainless steels showed quite similar. Characterization of intergranular stress corrosion cracking of 304. Scc is frequently observed to cause brittle behavior in otherwise ductile materials and can exhibit intergranular, transgranular, or mixed modes of crack propagation. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. This type of failure is known as stress corrosion cracking, often abbreviated to scc. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Introduction crystal plasticity is now classically used in material science to capture. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Stress corrosion cracking scc is a well know phenomena in conventional uhsss such as ph 174 and ph 188 46. Stress corrosion cracking international institute of.
Susceptible alloy tensile stress residual or applied scc can proceed in either of two ways. Transgranular stress corrosion cracking occurs mainly in chloride cracking of austenitic steels. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. Pdf modeling of inter and transgranular stress corrosion crack. An additional document titled addendum on circumferential scc was published in 1998 that specifically addressed the much lesscommon circumferential scc. The mechanism of cracking in both these modes and the conditions under which the transition from trans to intergranular cracking or vice versa occur are topics of much debate and research. Intergranular stress corrosion cracking of copper in. Intergranular and transgranular stress corrosion cracking of cu 30au. Intergranular cracks follow the grain boundaries in the metal. Intergranular stress corrosion cracking an overview. Is the transgranular stress corrosion cracking is because of chlorides present in the. Welded steel pipelines that are used to transport oil and gas under high pressure have been known to fail by stress corrosion cracking scc, and the. Stress corrosion cracking scc of magnesium mg alloys. Instances of tgscc have been associated with dilute solutions with ph values in the region of 6.